Top 10 Hollywood’s “It” Couples & How They First Met

8 Brad Pitt and Angelina Jolie

The relationship between this Hollywood couple has been featured on many magazine covers. Angelia Jolie and Brad Pitt are often in the news for their scandalous romance or their famous divorce. They first met on the set of Mr. & Mrs. Smith in 2004. The rest is history.

But, rumors about their relationship started circulating and Pitt was still married to Jennifer Aniston. The heartthrob eventually began to date Jolie and later married her. The couple seemed perfect, but after 12 years and six children, they broke up. Fans of Brangelina were devastated and hoped that they would reunite. They didn’t get back together, but they did keep in touch with their children.